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位置:首页 > 品牌 > Strem > (1S,2S)-(+)-[1,2-环己烷二胺-N,N'-双(3,5-二叔丁基亚水杨基)]氯化铬

(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride

(1S,2S)-(+)-[1,2-环己烷二胺-N,N'-双(3,5-二叔丁基亚水杨基)]氯化铬

品牌
Strem
CAS
219143-92-7
货号
24-0851
包装型号
规格纯度
参考价格
855 *本价格含增值税费
促销
服务
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数量
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产品名称:
219143-92-7
(1S,2S)-(+)-[1,2-Cyclohexanediamino-N,N'-bis(3,5-di-t-butylsalicylidene)]chromium(III) chloride
(1S,2S)-(+)-[1,2-环己烷二胺-N,N'-双(3,5-二叔丁基亚水杨基)]氯化铬
产品介绍:

Technical Notes :

1. Catalyst for the asymmetric ring-opening of mes o-epoxides and for the kinetic res olution of terminal epoxides. 2. Precatalyst for as ymmetric Diels -Alder and hetero Diels-Alder reactions.

3.Catalyst for copolymerization of CO2 and epoxides

4. Catalyst for enantios elective alkylation of tributyltin enolates .

5. Enantioselective addition of Me2Zn to aldehydes .

6.Enantios elective intramolecular addition of tertiary enamides to ketones.

7.Asymmetric iodocyclization.

8.Catalytic intermolecular linear allylic C-H animation.

9. Cocatalyst for enantios elective ring opening of epoxides with fluoride.

References:

1.Acc. Chem. Res., 2000, 33, 421. (review)

2.J.Am. Chem. Soc., 2000, 122, 7843.

3.J.Am. Chem.1998 63,403.

4. Acc. Chem. Res., 2004, 37, 836.

5. (a) J. Am. Chem. Soc., 2005, 127, 62. (b) Angew. Chem. Int. Ed., 2007, 46, 3701.

Strem

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