Technical Notes:
1. Used in the enantioselective racemic resolution of a range of 1 ,2-amino via liquid-liquid extraction ofalcohols.
References:
1. ChemSusChem 2018, 11, 178.
Strem
CALSELECT? Lithium tri-sec-butylborohydride, 1M in tetrahydrofuran
CALLERY? (+)-Diisopinocampheylchloroborane
CALLERY? Sodium mentholate
[S(R)]-N-[(S)-(2-Methylphenyl)[2-(diphenylphosphino)phenyl]methyl]-2-methyl-2-propanesulfinamide
[S(R)]-N-((R)-(2-(Diphenylphosphino)phenyl)(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)methyl]-2-methyl-2-propanesulfinamide
[S(R)]-N-[(S)-(2-Methylphenyl)[2- (diphenylphosphino)phenyl]methyl]-N,2-dimethyl-2-propanesulfinamide
[S(R)]-N-[(R)-[3,5-Bis(1,1-dimethylethyl)-4-methoxyphenyl][2-(diphenylphosphino)phenyl]methyl]-N,2-dimethyl-2-propanesulfinamide
[S(R)]-N-[(S)-(4-Methoxyphenyl)[2-(dicyclohexylphosphino)phenyl]methyl]-2-methyl-2-propanesulfinamide
[S(R)]-N-[(S)-[2-(Dicyclohexylphosphanyl)phenyl](4-(tert-butyl)phenyl)methyl]-N,2-dimethyl-2-propanesulfinamide
[S(R)]-N-((R)-(2-(Dicyclohexylphosphino)phenyl)(2,4,6-triisopropylphenyl)methyl)-N,2-dimethyl-2-propanesulfinamide
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