Technical Notes:
1.(In or Ga )/Ag/chiral phosphoric catalyst for asymmetric Hosomi-Sakurai reactions with N,O-aminals using allyl boronates.
References:
1.Angew. Chem. Int. Ed 2011, 50, 11121.
2.J. Àm. Chem. Soc. 2016, 138, 13119.
Strem
(3a'S,8a'S)-4',4',8',8'-四(3,5-二叔丁基苯基)-6'-羟基四氢螺环[环己烷-1,2'-6'-ox[1,3]二氧并[4,5-e][1,3,2]二氧磷, (3a'S,8a'S)-4',4',8',8'-Tetrakis(3,5-di-tert-butylphenyl)-6'-hydroxy-tetrahydrospiro[cyclohexane-1,2'-6'-ox[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine
(3aR,8aR)-四氢-6-羟基-2,2-二甲基-4,4,8,8-四(3,5-二异丙基-4-甲氧基苯基)-6-氧化物-[1,3]二氧并[4,5-e][1,3,2]二氧磷庚, (3aR,8aR)-Tetrahydro-6-hydroxy-2,2-dimethyl-4,4,8,8-tetrakis(3,5-diisopropyl-4-methoxyphenyl)-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine
(11aR)-3,7-双(4-氯苯基)-10,11,12,13-四氢-10,10,13,13-四甲基-5-羟基-二茚基[7,1-de:1', (11aR)-3,7-Bis(4-chlorophenyl)-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin
CALLERY? Methoxydiethylborane
三乙基硼烷-1,3-二氨基丙烷, CALLERY? Triethylborane-1,3-diaminopropane
CALLERY? Sodium?tert-amylate
[S(R)]-N-[(1S)-2-(Diphenylphosphanyl)-1-(2-(diphenylphosphanyl)phenyl)ethyl]-N,2-dimethyl-2-propanesulfinamide
[S(R)]-N-((S)-(2-(Diphenylphosphino)phenyl)(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)methyl]-2-methyl-2-propanesulfinamide
[S(R)]-N-[(R)-(2-Methylphenyl)[2- (diphenylphosphino)phenyl]methyl]-N,2-dimethyl-2-propanesulfinamide
[S(R)]-N-[(R)-[2-(Dicyclohexylphosphino)phenyl]-1-naphthalenylmethyl]-2-methyl-2-propanesulfinamide
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