Technical Notes
1. Ligand for the Ru-catalyzed direct amination of secondary alcohols using ammonia.
2.L igand for the Pd-catalyzed at- and ß-arylation of acyclic N-Boc amines.
3.Used in Pd-catalyzed enantioselective synthesis of ß2- and ß3- amino acids via asymmetric and regiodivergent c -H Functionalization of Boc-1 ,3-oxazinanes .
References:
1. Angew. Chem. Int. Ed. 2010, 49, 8130.
2. Angew. Chem. Int. Ed. 2014, 53, 2678.
3.Nat. Catal. 2019, 2, 882.
Strem