(11aR)-10,11,12,13-四氢-10,10,13,13-四甲基-5-羟基-3,7-二-2-萘-5-氧化物-二茚基[7,1-de: 1',7'-fg] [1,3,2]二氧杂磷霉素, (11aR)-10,11,12,13-Tetrahydro-10,10,13,13-tetramethyl-5-hydroxy-3,7-di-2-naphthalenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

(11bR)-4-羟基-2,6-双(2,6-二甲氧基苯基)-4-氧化物-二萘酚[2,1-d:1',2'-f][1,3,2]二氧磷, (11bR)-4-Hydroxy-2,6-bis(2,6-dimethoxyphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(3aS,8aS)-4,4,8,8-四(3,5-二叔丁基苯基)-2,2-双(4-氟苯基)-6-羟基四氢-6-氧化物-[1,3]二氧杂环[4,5-e][1,3,2]二氧磷, (3aS,8aS)-4,4,8,8-Tetrakis(3,5-di-tert-butylphenyl)-2,2-bis(4-fluorophenyl)-6-hydroxy-tetrahydro-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine

(3aS,8aS)-四氢-6-羟基-2,2-二甲基-4,4,8,8-四(3,5-二异丙基-4-甲氧基苯基)-6-氧化物-[1,3]二氧杂环[4,5-e][1,3,2]二氧磷庚, (3aS,8aS)-Tetrahydro-6-hydroxy-2,2-dimethyl-4,4,8,8-tetrakis(3,5-diisopropyl-4-methoxyphenyl)-6-oxide-[1,3]dioxolo[4,5-e][1,3,2]dioxaphosphepine

(11aR)-3,7-Bis [3,5-双(叔丁基)-4-甲氧基苯基] -10,11,12,13-四氢-10,10,13,13-四甲基-5-羟基[ 7,1-de:1',7'-fg] [1,3,2]二氧杂磷霉素, (11aR)-3,7-Bis[3,5-bis(tert-butyl)-4-methoxyphenyl]-10,11,12,13-tetrahydro-10,10,13,13-tetramethyl-5-hydroxy[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin

(3-(Tert-butoxy)-2',6'-diisopropyl-6-methoxy-[1,1'-biphenyl]-2-yl)dicyclohexylphosphane GPhos

CALSELECT? Sodium tri-sec-butylborohydride, 1M in tetrahydrofuran

CALLERY? N,N-Diethylaniline borane

[S(R)]-N-[(1R)-1-[2-(Diphenylphosphino)phenyl]ethyl]-2-methyl-2-propanesulfinamide

[S(R)]-N-[(1R)-1-[2-(Diphenylphosphino)phenyl]ethyl]-N,2-dimethyl-2-propanesulfinamide