Technical Notes:
1.Organocatalyst used in enantioselective intermolecular cross Rauhut-Currier reactions of activated alkenes with acrolein.
2.Used in phos phine-catalyzed asymmetric umpolung addition of trifluoromethyl ketimines to Morita-Baylis- Hillman carbonates.
3.Organocatalyst for 4 +2 anulation of electron-deficient dienes and vinyl ketones .
References:
1.Chem. Commun.. 2016, 52, 7612
2.Angew. Chem. Int. Ed. 2016, 55, 13316.
3.Adv. Synth. Catal. 2018, 360, 682.
Strem