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Hydrido(dimethylphosphinous acid-kP)[hydrogen bis(dimethylphosphinito-kP)]platinum(II) Ghaffar-Parkins catalyst

(二甲基膦酸)铂(II)氢化络合物

品牌
Strem
CAS
173416-05-2
货号
78-0725
包装型号
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参考价格
2385 *本价格含增值税费
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产品名称:
173416-05-2
Hydrido(dimethylphosphinous acid-kP)[hydrogen bis(dimethylphosphinito-kP)]platinum(II) Ghaffar-Parkins catalyst
(二甲基膦酸)铂(II)氢化络合物
产品介绍:

Technical Note:

1. Widely used in complex multi-step organic syntheses. This mild hydration catalyst converts hindered and acid/base sensitive nitriles to amides. The amide is released from the metal coordination sphere preventing further hydrolysis to acid. Typically . turnover frequency (TOF) ranges from 16 to 380 h-1 depending on steric factors. For optimal results avoid the presence of coordinating anions especially cyanide and halide.

References:

1.J.Org.Chem.2004, 69, 2327.

2.Org. Lett, 2006. 8. 2643

3.J. Org Chem.. 2009. 74. 5405.

4.Tetrahedron Lett.,2010,51,6422

5. Appl. Sci. 2015, 5, 380. (catalyst review article)

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