Technlcal Notes:
1.Precursor for the preparation of a palladium catalyst used in the carbonylative arylation of ketones, yielding vinylbenzoate compounds.
2.Precursor for the preparation of a palladium catalyst used in the B uchwald-Hartwig amination of (hetero)aryI chlorides.
3.Precursor for the preparation of a palladium catalyst used in the arylative doaromatization of phenols.
4.Versatile palladium precursor for the preparation of palladium catalysts used in the cross-coupling of aryl chlorides and amines . conversion of aryl triflates to aryl fluorides. and the a-arylation of aldehydes .
References: 1.Chem. Eur. J.. 2012, 18. 1 5592. 2.Eur. J. Org- Chem., 2012, 3972. 3.J. Am. Chem. Soc., 2011. 133, 9282. 4.Chem. Eur. J.2010. 16, 1983. 5.Science, 2009. 325, 1661. 6.Org. Lett., 2008.10, 4561 .
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