Technical Notes:
1. A homogeneous hydrogenation catalyst which operates under mild conditions.
2.Catalyst for the decarbonylation of aldehydes.
3.Catalyst for regio- and stereoselective allylic substitution reactions.
4.Alkyne hydro-phosphorylation
5. Heck-type reaction with a,ß-unsaturated esters.
Rh(l)-catalyzed ortho-alkenylation of aromatic ketimines with alkynes Allylic alcohol-olefin coupling.
References:
1.Progress Inorg. Chem., 1984, 28.
2.J. Org. Chem., 1992, 57, 5075
3.Encyclopedia of Reagents for Organic Synthesis, 1995, Vol. 2, 1253.
4.Org. L ett., 1999, 1, 1929.
5.Angew. Chem. Int. Ed., 2001, 40, 1929.
6.Chem. Commun., 2003, 2438.
7.Org. Lett., 2003, 5, 2759 .
8.J. Org. Chem., 2002, 67, 3945.
Strem
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