Technical Notes:
1. Precursor for asymmetric hydrogenation reactions.
2. Rh-catalyzed carbozincation of ynamides.
References:
1. J. Org. Chem., 1999, 64, 5593.
2. J. Org. Chem., 2009, 74, 7849.
Strem
(+)-1,2-Bis((2S,5S)-2,5-diethylphospholano)benzene(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
(+)-1,2-双((2S,5S)-2,5-二乙基膦)苯(环辛二烯)三氟甲磺酸铑(I)
3-二异丙基膦-2-(N,N-二甲基氨基)-1,5-环辛二烯)铑(I)六氟磷酸盐, 3-Di-i-propylphosphino-2-(N,N-dimethylamino)-1H-indene(1,5-cyclooctadiene)rhodium(I) hexafluorophosphate
(R)-(-)-4,12-Bis(di-3,5-xylylphosphino)[2.2]paracyclophane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
(R)-(-)-4,12-双(二-3,5-二甲苯基膦基)[2.2]对环芳烷(1,5-环辛二烯)铑(I)四氟硼酸盐
Di-mu-methoxobis(1,5-cyclooctadiene)dirhodium(I)
双(1,5-环辛二烯)二甲氧基二铑
(-)-2,3-双[(2R,5R)-2,5-二甲基膦酰]马来酸酐(1,5-环辛二烯)铑(I)三氟甲烷磺酸盐, (-)-2,3-Bis[(2R,5R)-2,5-dimethylphospholanyl]maleic anhydride(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate
Rhodium(III) acetylacetonate
乙酰丙酮铑
Rhodium powder
六氯铑酸钠水合物, Sodium hexachlororhodate(III) hydrate
(S)-(+)-2,2',6,6'-四甲氧基-4,4'-二(二苯基膦基)-3,3'-联吡啶(1,5-环辛二烯)铑(I)四氟硼酸, (S)-(-)-2,2',6,6'-Tetramethoxy-4,4'-bis(diphenylphosphino)-3,3'-bipyridine(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate
烯丙基氯化[1,3-双(2,6-二-异丙苯基)-4,5-二氢咪唑-2-基]钯, Allylchloro[1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazol-2-ylidene]palladium(II)