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Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]

(S)-钌(醋酸)2(H8-BINAP)

品牌
Strem
CAS
142962-95-6
货号
44-0167
包装型号
规格纯度
参考价格
1245 *本价格含增值税费
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产品名称:
142962-95-6
Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]
(S)-钌(醋酸)2(H8-BINAP)
产品介绍:

Technical Notes:

1. Biaryl bisphosphine ligand. The Ha-BINAP ligand, as the ruthenium complex, catalyzes hydrogenation of unsaturated carboxylic acids to a higher ee than does BINAP. (Ref. 1,2)

2.The ruthenium catalyzed hydrogenation of aryl propenoic acid to produce the drug Ibuprofen.

References:

1. J. Org. Chem., 1996, 61, 5510.

2. Topics Organometal. Chem. 2004, 6, 63 (review).

Strem

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