Technical Notes:
1.Catalyst for asymmetric hydrogenation of a and B-keto esters.
2.Catalyst for asymmetric hydrogenation of a,B unsaturated acids.
References:
1.EP1160237 (2001 ).
2. US5801261 (1998).
Strem
氯(五甲基环戊二烯)钌(Ⅱ), Chloro(pentamethylcyclopentadienyl)ruthenium(II) Tetramer
Diacetato{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦]-4,4'-双- 1,3 -苯并二氧杂环戊烯}钌(II), Diacetato{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(R)-dm-segphos?]
N-[(1R,2R)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (R,R)-Ts-DENEB
二氯[(R)-5,5′-双[二(3,5-二甲苯基)膦]-4,4′-二-1,3-苯并二噁茂][(1R,2R)-1,2-二苯基乙二胺]钌(II), Dichloro{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(R)-dm-segphos?][(R,R)-dpen]
[双(吡唑-1-基)(乙酰氨基)氢化硼酸](对伞花烃)三氟甲磺酸钌(II), [Bis(pyrazol-1-yl)(acetimino)hydridoborato](p-cymene)ruthenium(II) trifluoromethanesulfonate
(R)-2-[(R)-2-(二苯基膦)二茂铁基]-4-异丙基-2-噁唑啉三苯基膦氯化钌(II)络合物, (+)-Dichloro[(4R)-4-(i-propyl)-2-{(R)-2-(diphenylphosphino)ferrocenyl}oxazoline](triphenylphosphine)ruthenium(II)
Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]diruthenate(II) [NH2Me2][{RuCl((R)-H8-binap)}2(mu-Cl)3]
二甲基氨基二氯三(μ-氯)双[(R)-(+)-2,2'-双(二苯基膦基)-5,5',6,6',7,7',8,8'-八氢-1,1'-联萘]二钌(Ⅱ)
Hexaammineruthenium(II) chloride
六氨合钌氯
(1,3-双(2,6-二异丙基)-4-((4-乙基-4-甲基哌嗪-1-鎓-1-基)甲基)咪唑烷-2-亚基)(2-异丙氧基苄基)钌(II)二氯化物,氯化二水合物,Fixcat, (1,3-Bis(2,6-diisopropylphenyl)-4-((4-ethyl-4-methylpiperzain-1-ium-1-yl)methyl)imidazolidin-2-ylidene)(2-isopropoxybenzylidene)ruthenium(II)dichloride chloride dihydrate FixCat
[1,3-双(2,6-二异丙基苯基)咪唑烷-2-亚基)(2-异丙氧基-5-硝基亚苄基)二碘化钌(II),nitro-GrelaI2SIPr, [1,3-Bis(2,6-di-i-propylphenyl)imidazolidin-2-ylidene)(2-i-propoxy-5-nitrobenzylidene) ruthenium(II) diiodide nitro-Grela I2 SIPr