Technical Notes:
1.Catalyst for asymmetric hydrogenation of a and B-keto esters.
2.Catalyst for asymmetric hydrogenation of a,B unsaturated acids.
References:
1.EP1160237 (2001 ).
2. US5801261 (1998).
Strem
Chloro{[(1S,2S)-(+)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
{[(s,s)-(-)-2-氨基-1,2-二苯乙基](4-甲苯磺酰)氨基}(p-异丙基甲苯)氯化钌(II)
Chloro{[(1R,2R)-(-)-2-amino-1,2-diphenylethyl](4-toluenesulfonyl)amido}(p-cymene)ruthenium(II)
氯{[(1R,2R)-(-)-2-氨-1,2-二苯乙基](4-甲苯磺酰)氨}(p-异丙基甲苯)钌(II) )钌(II)
二乙酸根[(S)-(-)-5,5′-双[二(3,5-二甲苯基)膦基]-4,4′-二-1,3-苯并二噁茂]钌(II), Diacetato{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}ruthenium(II) Ru(OAc)2[(S)-dm-segphos?]
Dichloro{(S)-(-)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2S)-(+)-1,1-bis(4-methoxyphenyl)-3-methyl-1,2-butanediamine]ruthenium(II) RuCl2[(S)-xylbinap][(S)-daipen]
二氯{(S )-(-)-2,2'- 双[二(3,5-二甲苯基)膦]-1,1'-联萘} [(2S)-(+)-1,1-二(4-甲氧基苯基)-3 -
二氯{(S)-(-)-5,5'-二[双(3,5-二甲基苯l)磷酰]-4,4'-二-1,3-二氧苯}[(1S,2S)-(-)-1,2-二苯基二胺]钌(II), Dichloro{(S)-(-)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}[(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II) RuCl2[(S)-dm-segphos?][(S,S)-dpen]
二氯[(S )-(+)- 4,12 -双(二(3,5 -二甲苯基)膦)-[2.2],对环芳烷] [(1R,2R)-(+)- 1,2 -二苯基]钌, Dichloro[(S)-(+)-4,12-bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane][(1R,2R)-(+)-1,2-diphenylethylenediamine]ruthenium(II)
Dichlorotricarbonylruthenium(II) dimer
二氯三羰基钌
二甲基铵二氯三(μ-氯)双{(R)-(+)-5,5'-双[二(3,5-二甲苯基)膦基] -4,4'-双-1,3-苯并间二氧杂环戊烯}二钌(II), Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-5,5'-bis[di(3,5-xylyl)phosphino]-4,4'-bi-1,3-benzodioxole}diruthenate(II) [NH2Me2][{RuCl((R)-dm-segphos?)}2(mu-Cl)3]
Hexaammineruthenium(III) chloride
三氯化六铵合钌
[1,3-双(2,4,6-三甲基苯基咪唑烷-2-亚基)(三环己基膦)-(2-氧代亚苄基)氯化钌(VI), [1,3-Bis(2,4,6-trimethylphenylimidazolidin-2-ylidene)](tricyclohexylphosphine)-(2-oxobenzylidene)ruthenium(II) chloride LatMet