您好，欢迎来到试剂仪器网！ [登录] [免费注册]

Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos?)]Cl

氯[(S)-(+)-5,5′-双[二(3,5-二-叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂](p-伞花素)氯化钌(II)

品牌

Strem

CAS

944451-33-6

货号

44-0103

包装型号

规格纯度

价格

795 元 *本价格含增值税费

促销

数量

QQ 微信

添加到订购单查看订购单

产品名称：

944451-33-6
Chloro{(S)-(+)-5,5'-bis[di(3,5-di-t-butyl-4-methoxyphenyl)phosphino]-4,4'-bi-1,3-benzodioxole}(p-cymene)ruthenium(II) chloride [RuCl(p-cymene)((S)-dtbm-segphos?)]Cl
氯[(S)-(+)-5,5′-双[二(3,5-二-叔丁基-4-甲氧基苯基)膦]-4,4′-二-1,3-苯并二噁茂](p-伞花素)氯化钌(II)

产品介绍：

Technical Notes:

1.See 15-0066.

2.Biaryl bisphosphine ligand with narrow dihedral angle. The DTBM SEGPHOS ligand, as the ruthenium complex, gives superior enantioselectivity and diastereoselectivity through dynamic kinetic resolution in the asymmetric hydrogenation of a-substituted-ß-ketoesters useful in the synthesis of carbapenum antibiotics.

References:

1. Adv. Synth. Cat., 2001, 343, 264.

Strem

推荐产品

(S)-钌(醋酸)2(H8-BINAP), Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-5,5',6,6',7,7',8,8'-octahydro-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-H8-binap]

N-[(1S,2S)-1,2-二苯基-2-(2 -(4 -甲基苄氧基)乙基氨基)乙基] -4-甲基苯磺酰胺(氯)钌(II), N-[(1S,2S)-1,2-Diphenyl-2-(2-(4-methylbenzyloxy)ethylamino)-ethyl]-4-methylbenzene sulfonamide(chloro)ruthenium(II) (S,S)-Ts-DENEB

双[二(3,5-二甲苯基)膦]-1,1'-联萘(2R)-(-)-1-(4-甲氧基苯基)-1-(4-甲氧基- KC)-3 -甲, Chloro{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}[(2R)-(-)-1-(4-methoxyphenyl)-1’-(4-methoxyphenyl-kC)-3-methyl-1,2-butanediamine]ruthenium(II) (R)-RUCY?-XylBINAP

二氯{(R)-2,2'-双[二(4-甲基苯基)]-1,1'-联萘}[(1R,2R)-2-胺-1-苯基丙基二苯基膦]钌(II), Dichloro{(R)-2,2'-bis[bis(4-methylphenyl)]-1,1'-binaphthyl}[(1R,2R)-2-amino-1-phenylpropyldiphenylphosphine]ruthenium(II)

二氯[(S)-(-)-2,2',6,6'-四甲氧基-4,4'-双(二(3,5-二甲苯基)膦)-3,3'-二吡啶][(1S,2S)-(-)-1,2-二苯基乙二胺]铷(II), Dichloro[(S)-(-)-2,2',6,6'-tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine][(1S,2S)-(-)-1,2-diphenylethylenediamine]ruthenium(II)

二甲基铵二氯三(μ-氯)双{(R)-(+)-2,2'-双[二(3,5-二甲苯基)膦基] -1,1'-联萘}二钌(II), Dimethylammonium dichlorotri(mu-chloro)bis{(R)-(+)-2,2'-bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl}diruthenate(II) [NH2Me2][{RuCl((R)-xylbinap)}2(mu-Cl)3]

二[(S)-(+)-5,5'-双(二苯基膦)-4,4'-双-1,3 -二氧基苯, Dimethylammonium dichlorotri(mu-chloro)bis[(R)-(+)-5,5'-bis(diphenylphosphino)-4,4'-bi-1,3-benzodioxole]diruthenate(II) [NH2Me2][{RuCl((R)-segphos?)}2(mu-Cl)3]

二氯[N1,N1-二甲基-N2-[2-(苯硫基-kappaS)乙基]-1,2-乙二胺-kappaN1,kappaN2](三环己基膦)钌(II), Dichloro[N1,N1-dimethyl-N2-[2-(phenylthio-κS)ethyl]-1,2-ethanediamine-κN1,κN2](tricyclohexylphosphine)ruthenium(II)

[1,3-双(2,4,6-三甲基苯基)咪唑烷-2-亚基)-(2-异丙氧基-5-硝基亚苄基)二碘化钌(II) nitro-Grela I2, [1,3-Bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene)-(2-i-propoxy-5-nitrobenzylidene) ruthenium(II) diiodide nitro-Grela I2

二氯[(S)-(-)-2,2'-双(二苯基膦基)-1,1'-联萘[(S)-(-)-2-(α-甲基甲酰胺基)-1H-苯并咪唑]钌(II), Dichloro[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl][(S)-(-)-2-(α;-methylmethanamine)-1H-benzimidazole]ruthenium(II)