Technical Note:
1. Chiral ligand for the rhodium-catalyzed asymmetric hydrogenation of a-ß unsaturated substrates.
References:
1. J. Am. Chem. Soc., 2009, 131, 6683.
2. Angew. Chem. Int. Ed., 2008, 47, 3180.
3. Patent W02009065856 .
Strem
(R)-(+)-7-双(3,5-二叔丁基苯基)膦基-7'-[(吡啶-2-基甲基)氨基]-2,2',3,3'-四氢-1,1'-螺二茚满, (R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(pyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane
(S)-(-)-7 -〔4(S)-(苄基)恶唑-2-基]-7-二苯基膦基-2,2',3,3'-四氢-1,1'-螺二氢茚, (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,2’,3,3’-tetrahydro-1,1'-spirobiindane
p-Tolyldiphenylphosphine
二苯基甲苯基磷
Tri-n-butylphosphine
三正丁基膦
Tricyclohexylphosphine
三环己基磷
(2R,3R)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2-甲基-2,3-二氢苯并[d] [1,3]氧磷杂环戊二烯, (2R,3R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole
(2S,2'S,3S,3'S)-3,3'-二叔丁基-4,4'-二甲氧基-2,2',3,3'-四氢-2,2'-二苯并[d][1,3]氧杂磷杂戊环, (2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-dimethoxy-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole
Triethylphosphonium tetrafluoroborate
四氟硼酸三乙基鏻
Trihexyl(tetradecyl)phosphonium decanoate
2-甲基-2-[(十二基硫硫代碳酰)硫]丙酸
(2S,2'S,3S,3'S)-3,3'-二叔丁基-2,2'-二乙基-2,2',3,3'-四氢-4,4'-联苯并[d][1,3]氧磷, (2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-2,2'-diethyl-2,2',3,3'-tetrahydro-4,4'-bibenzo[d][1,3]oxaphosphole
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