Technical Note:
1. Chiral ligand for the rhodium-catalyzed a symmetric hydrogenation of a-ß unsaturated substrates .
References:
1.J. Am. Chem. Soc., 2009, 131, 6683.
2.Angew. Chem. Int. Ed., 2008, 47, 31 80.
3.Patent W02009065856.
Strem
(S)-(-)-7-双(3,5-二叔丁基苯基)膦基-7'-[(3-甲基吡啶-2-基甲基)氨基]-2,2',3,3'-四氢-1,1'-螺二茚满, (S)-(-)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane
(11aR)-(+)-5,6,10,11,12,13-六氢-5 -苯基-4H-二茚并[7,1-cd:1',7'-ef〕磷, (11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin
Triallylphosphine
三烯丙膦
Tri-t-butylphosphine
三叔丁基膦
Tri(m-chlorophenyl)phosphine
三(3-甲氧基苯基)膦
(R)-3-(叔丁基)-4-(2,6-二甲氧基苯基)-2,3-二氢苯并[d] [1,3]氧杂磷杂环戊烷, (R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole
(2S,2'S,3S,3'S)-3,3'-二叔丁基-4,4'-双(2,6-二甲氧基苯基)-2,2',3,3'-四氢-2,2-二苯并[d][1,3]氧杂磷杂戊环, (2S,2'S,3S,3'S)-3,3'-Di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole
(R)-1-(3-(叔丁基)-2,3-二氢苯并[d][1,3]氧杂磷杂环己烷-4-基)-2,5-二苯基-1H-吡咯, (R)-1-(3-(tert-Butyl)-2,3-dihydrobenzo[d][1,3]oxaphosphol-4-yl)-2,5-diphenyl-1H-pyrrole
Tris(3-hydroxypropyl)phosphine
三(3-羟基丙基)膦
[2,4,6-三甲氧基苯基]二环己基鏻四氟硼酸盐, [2,4,6-Trimethoxyphenyl]dicyclohexylphosphonium tetrafluoroborate