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(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(11bR)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英

品牌

Strem

CAS

922711-75-9

货号

15-1378

包装型号

规格纯度

98%, (99% ee)

参考价格

1530 元 *本价格含增值税费

促销

数量

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产品名称：

922711-75-9
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin
(11bR)-8,9,10,11,12,13,14,15-八氢-4-羟基-2,6-二甲基-2-萘基-4-氧化物二萘并[2,1-d:1',2'-f][1,3,2]二噁磷杂庚英

产品介绍：

Technical Notes:

1.The preparation of binaphthol monophosphoric acid derivatives.

2.Organocatalyst developed for the diastereo- and enantioselective 1 4-conjugate addn. of a variety of

ß-ketoesters to nitroolefins, employed in the addn. re action, providing the corre sponding nitroalkanes in high yield (up to 97%) with moderate diastereoselectivities (up to 2.6:1 dr) and enantioselectivities (up to 58% ee).

References:

1.JP 4725757, EP 1038877, US 6274745, 2000-3-21.

2. Lett. in Org. Chem., 2010, 7, 219-225.

Strem

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