Technical Notes:
1. Ligand used in the enantioselective, rhodium-catalyzed hydrogenation of substituted olefins, such as N-acetyldihydroamino
acids, enamides, and unsaturated acids .
2. Ligand used in the enantioselective, iridium-catalyzed allylic substitution of allyl acetates containing only a single substituent in the 1 or 3 position.
3.L igand use in the rhodium-catalyzed, amide directed, asymmetric hydroboration reaction.
4.L igand used in asymmetric conjugate addition of aryl boronic acids to dihydronitronaphthalenes .
5. Ligand used in the rhodium-catalyzed asymmetric intramolecular 1,4 addition.
References: 1.J. Am. Chem. Soc., 2000, 122, 1 1539. 2.Adv. Synth. ( atal., 2003, 345, 308. 3.Adv. Synth. Catal., 2002, 344, 1 003. 4.Chem. Comm, 1999, 741 . 5.Eur. J. Inorg. Chem., 2002, 2569. 6.J. Am. Chem. Soc., 2008, 130, 3734. 7.Ad. Synth. Catal, 2012, 354, 2433. 8.J. Org. Chem., 2013, 78, 2736.
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