Technical Notes:
1.Suzuki-Miyaura Coupling of Aryl Mesylates and alkenyl tosylate and mesylate bearing alkyl, methoxy, aldehyde, keto, nitrile, ester. and heteroary substitution.
2.Sonogashira Coupling of Aryl Mesylates, R' = alkyl, aryl; R = C(O)R, cooMe, cHO, CN.
3.Buchwald-Hartwig Amination of Aryl Mesylates, R = cyano, chloro, methoxy, keto, ester and etc.
4.Additional catalyzed reactions include Cyanation of functional Aryl Mesylates and Chlorides (R Ref. 4,5); Hiyama Coupling of Aryl Mesylates (Ref. 6); Direct Arylation of Heterocycles with Aryl Mesylates (Ref. 7); Borylation of Aryl Mesylates (Ref. 8).
References: 1.Angew. Chem. Int. Ed., 2008, 47, 8059. 2.Chem. Eur. J., 2010, 16, 9982. 3.Angew. Chem. Int. Ed., 2008, 47, 6402. 4.Angew. ( hem. Int. Ed., 2010, 49, 8918. 5.Org. L ett., 2011, 13, 648. 6.Org. L ett., 2009, 11, 31 7. 7.Chem. Eur. J., 2011, 1 7, 761. 8.Chem. Eur. J., 2011, 1 7, 6913. 9.Chem. Commun., 2011, 47, 8328.
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