Technical Notes:
1.With rhodium forms a highly active catalyst for the hydroformylation of a olefins .
2.The hydroformylation of functionalized a-olefins is highly regios elective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality
3. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step
References: 1.US Patent 47 69498. 2.J. Am. Chem. Soc., 1993, 1 15, 2066. 3.Organometallics, 1995, 14, 3832. 4.J. Mol. Catal. A, 2005, 232, 41. 5.J. Org. Chem. 1995, 60, 7078. 6.J. Org. Chem. 2007, 72, 1871. 7.Chem. Rev.1999, 99, 3329.Strem