Technical Notes:
1. Ligand for Cu- catalyzed enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines to prepare a chiral amines .
2.Used in the Pd-catalyzed allylation of aliphatic alcohols.
3.Ligand for Rh-catalyzed enantioselective carbonyl hydroacylation.
4.Ligand for cobalt-catalyzed asymmetric alkene hydroge nation.
References:
1.J. Am. Chem. Soc., 2003, 125, 1692.
2.J. Org. Chem., 2003, 68, 8092.
3.J. Am. Chem. Soc.. 2008, 130, 2916.
4.Science, 2013, 342, 1076.
Strem