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位置:首页 > 品牌 > Strem > (5aR,10bS)-(+)-5a,10b-二氢-2-(五氟苯基)-4H,6H-茚并[2,1-b][1,2,4]三唑并[4,3-d][1,4]恶唑嗡 四氟硼酸

(5aR,10bS)-(+)-5a,10b-Dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate

(5aR,10bS)-(+)-5a,10b-二氢-2-(五氟苯基)-4H,6H-茚并[2,1-b][1,2,4]三唑并[4,3-d][1,4]恶唑嗡 四氟硼酸

品牌
Strem
CAS
872143-57-2
货号
07-0415
规格纯度
min. 98%
参考价格
2235 *本价格含增值税费
促销
服务
  • 原厂保证
  • 包邮
  • 增值税票
数量
-+
产品名称:
872143-57-2
(5aR,10bS)-(+)-5a,10b-Dihydro-2-(pentafluorophenyl)-4H,6H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazinium tetrafluoroborate
(5aR,10bS)-(+)-5a,10b-二氢-2-(五氟苯基)-4H,6H-茚并[2,1-b][1,2,4]三唑并[4,3-d][1,4]恶唑嗡 四氟硼酸
产品介绍:

Technical Notes:

1.Scope of the asymmetric intramolecular Stetter recation catalyzed by chiral nucleophilic triazolinylideneCarbens

2.Catalytic asymmetric Stetter reaction onto vinyl phosphine oxide and vinyl phosphonates .

3.N-Heterocyclic carbene catalyzed asymmetric hydration: Direct synthesis of a-protio and a-deuterio, a chloro and a-fluoro carboxylic acids

4.Chemoselective conversion of a-unbranched aldehydes to amides, esters and carboxylic acids by NHC-catalysis.

5.Extending the Stetter reaction with 1-6 acceptors .

6.N-Heterocyclic carbene-catalyzed/L ewis acid strategy for the stereoselective synthesis of spirocyclic

oxindole -dihydropyranones.

7.Access to P-stereogenic phosphinatesviaN-heterocycle

carbene- catalyzed desymmetrization of bisphenols.

8.N-Heterocyclic carbene catalyzed intramolecular nucleophilic substitution: Enantioselective construction of all carbon quaternary stereocenters.

Strem

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