Technical Notes:
1. Reagent used in the highly enantio- and diastereoselective, catalytic intramolecular Stetter reaction.
2. Enantioselective synthesis of ß-hydroxy and ß-amino esters.
3.Organocatalytic iminium ion/carbene reaction cascade for the formation of 2,4-disubstituted cyclopentenones .
4. Synthesis of allo- and epi-lnositol via the NHC-catalyzed carbocyclization of carbohydrate-derived dialdehydes.
References: 1.J. Org. Chem., 2008,73, 2033. 2.J. Am. Chem. Soc., 2006, 128, 2552. 3.Org. L ett., 2008, 10, 3141. 4.Org. L ett., 201 o, 12, 5052. 5.Org. Lett., 2011, 13, 4790. 6. J. Org. Chem., 2014,79, 5088.
Strem
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